Glass-filled polyamides
products
- Examid® PA66 GF30 — glass-filled, heat-stabilized polyamide 66
- Examid® PA66 GF50 — high-modulus 50% glass-filled heat-stabilized polyamide 66, metal replacement
- Glass-Fiber-Reinforced Polyamide Examid PA6 GF10-I
- Modified Glass-Filled Polyamide Examid PA6 GF20
- Long-Glass-Fiber-Filled Polyamide Examid PA6 LGF30
- Polyamide with improved surface quality Examid PA6 GFGB30-6231
- Glass-Filled Polyamide Armamid PA6 GF30-1T
- Glass-Filled Polyamide PA66 GF25 for Thermal Breaks
- High-Modulus Glass-Filled Polyamide Examid PA6 GF50 R10
- Glass-Filled Frost-Resistant Polyamide Examid PA6 GF30 62100i
- Glass-filled polyamide PA6 210 KS premium grade (OST 6-11-498-79)
- Glass-filled polyamide PA610 KS (GOST 17648-83)
- Glass-Filled Polyamide PA66 KS, Premium Grade (OST 6-11-498-79)
- Glass-Filled Flame-Retardant Polyamide Examid PA6 GF20 FR NC
- Glass-filled flame-retardant polyamide Examid PA6 GF25-FR 7035
- Glass-filled polyamide Examid PA6 GF10
- Glass-Filled Polyamide Examid® PA6 GF30 — Base Grade for Series Injection Molding
- Glass-Filled Polyamide for Laser Marking Examid® PA6 GF30 LM
New polyamide selection tools on the PA6 GF30 page
We have built a dedicated technical page for glass-filled PA6 GF30 polyamides: a comparison radar of 13 grades, interactive selection by application, an injection-moulding machine diagram with 7 temperature zones, and a full TDS table for Examid® PA6 GF30 / HI / LM / 62100i.
Go to the PA6 GF30 hub page →New polyamide selection tools on the PA6 GF50 page
We have built a dedicated technical page for glass-filled PA6 GF50 polyamide (50% glass fibre, modulus ≈16 500 MPa): a comparison radar, interactive selection by application, comparison with PA66 GF50 / PA66 CF30 / PA6 LGF40 and a full TDS table for Examid® PA6 GF50 R10.
Go to the PA6 GF50 hub page →Glass-filled polyamides (PA GF) are engineering thermoplastics based on the polyamides PA6, PA66, PA610, PA612 and PA12, reinforced with 10–50% glass fibre. Adding glass fibre increases the modulus of elasticity by a factor of 3–4, raises tensile strength by 80–120%, lifts the HDT/A heat resistance from 60 °C to 200–250 °C, and lowers linear moulding shrinkage from 1,4–1,8% to 0,3–0,6%. This makes PA-GF the material of choice for metal replacement in the automotive industry, thermal insulation of aluminium profiles, power-tool housings and load-bearing furniture-fitting components.
Material Wizard manufactures and supplies the Examid® line of glass-filled polyamides (PA6 GF10–GF50, PA66 GF30/GF50, specialised HI / LM / FR / cold-resistant / LGF modifications) and Armamid, and also imports BASF Ultramid, DuPont Zytel, Lanxess Durethan, DSM Akulon, Solvay Technyl, EMS-Grivory, Evonik Vestamid, Akro-Plastic Akromid and RadiciGroup Radilon grades. We select the material to match your drawing, the part's temperature regime and the parameters of your injection-moulding machine.
Key technical properties of PA6-GF30 and PA66-GF30
The figures are given for standard compounds in the dry-as-moulded (DAM) state. Actual lot values are stated in the material's technical data sheet.
| Property | PA6-GF30 | PA66-GF30 | Method |
|---|---|---|---|
| Density | 1,36 g/cm³ | 1,37 g/cm³ | ISO 1183 |
| Tensile modulus of elasticity | 9 500 MPa | 10 000 MPa | ISO 527 |
| Tensile strength | 175 MPa | 185 MPa | ISO 527 |
| Elongation at break | 3,5% | 3,0% | ISO 527 |
| Flexural modulus of elasticity | 9 000 MPa | 9 500 MPa | ISO 178 |
| Charpy notched impact strength (23 °C) | 11 kJ/m² | 12 kJ/m² | ISO 179/1eA |
| Heat deflection temperature (HDT/A, 1,8 MPa) | 200 °C | 250 °C | ISO 75 |
| Melting temperature | 220 °C | 260 °C | ISO 11357 |
| Processing temperature (melt) | 260–290 °C | 280–310 °C | TDS |
| Mould temperature | 80–100 °C | 80–120 °C | TDS |
| Water absorption over 24 h at 23 °C | 1,3% | 1,1% | ISO 62 |
| Water absorption at equilibrium (23 °C / 50% RH) | 2,6% | 2,2% | ISO 62 |
| Linear shrinkage along the flow | 0,3–0,5% | 0,4–0,6% | ISO 294-4 |
| Linear shrinkage across the flow | 0,8–1,2% | 0,9–1,3% | ISO 294-4 |
| Volume resistivity | 10¹⁴ Ohm·cm | 10¹⁴ Ohm·cm | IEC 60093 |
| Limiting oxygen index LOI (without flame retardants) | 23% | 25% | ISO 4589 |
How to choose a glass-filled polyamide — methodology
Step 1. Part operating temperature
| Operating temperature | Recommended grade |
|---|---|
| Up to 90 °C, no contact with hot liquids | PA6-GF30 (Examid® PA6 GF30, Armamid PA6 GF30-1T) |
| 90–130 °C, intermittent heating | PA6-GF30 with a heat stabiliser or PA66-GF30 |
| 130–170 °C, continuous load | Examid® PA66 GF30 with HSL stabilisation, analog of Zytel 70G30HSLR |
| 170–230 °C, under-hood area | PPA-GF (polyphthalamide) — a separate category, not a GF polyamide |
Step 2. Level of mechanical load
| Application | Recommended filler level |
|---|---|
| Decorative and lightly loaded parts | GF10–GF15 (low abrasiveness, better surface) |
| Device housings, medium-load brackets | GF20–GF25 |
| Standard structural parts (most cases) | GF30 — the optimum of stiffness, mouldability and price |
| Metal replacement, high-modulus parts | GF40–GF50 (Examid® PA66 GF50, Examid® PA6 GF50 R10) |
| Load-bearing parts with maximum impact strength | LGF — long glass fibre (Examid® PA6 LGF30) |
Step 3. Special requirements
| Requirement | Modification |
|---|---|
| Impact resistance without loss of stiffness | HI — Examid® PA6 GF30-I |
| Laser marking of the housing | LM — Examid® PA6 GF30 LM |
| Self-extinguishing V-0 (UL 94) | FR — Examid® PA6 GF30 LM |
| Operation at -40 °C and below | cold-resistant — Examid® PA6 GF30 62100i |
| Improved surface (visible parts) | GFGB with mineral filler — Examid® PA6 GFGB30-6231 |
| Thermal break for aluminium profiles | PA66 GF25 for thermal breaks |
| Contact with fuel, oils, biofuel | PA610-GF, PA612-GF |
Analogs of imported grades
| Imported grade | Material Wizard analog | Purpose |
|---|---|---|
| BASF Ultramid B3WG6 | Examid® PA6 GF30 | Standard PA6-GF30, housings, brackets |
| BASF Ultramid A3WG6 | Examid® PA66 GF30 | PA66-GF30, heat-stable parts |
| BASF Ultramid A3WG10 | Examid® PA66 GF50 | High-modulus PA66, metal replacement |
| DuPont Zytel 70G30HSLR | Examid® PA66 GF30 (HSL) | Long-term service at 150 °C | Long-term service at 150 °C |
| DuPont Zytel 70G50HSLR | Examid® PA66 GF50 | High-modulus, heat-resistant |
| Lanxess Durethan BKV30H1.0 | Examid® PA6 GF30 | PA6-GF30 with improved flow |
| DSM Akulon K224-G6 | Examid® PA6 GF30 | Standard PA6-GF30 |
| Solvay Technyl A218V30 | Examid® PA66 GF30 | Standard PA66-GF30 |
| Akro-Plastic Akromid B3 GF30 1 | Examid® PA6 GF30 | PA6-GF30 economy segment |
| RadiciGroup Radilon S RV300W | Examid® PA6 GF30 | PA6-GF30 for automotive |
| GOST PA6-211 KS | PA6 210 KS premium grade (OST 6-11-498-79) | Tender supplies |
| GOST PA66 KS | PA66 KS premium grade (OST 6-11-498-79) | Tender supplies |
| GOST PA610 KS | PA610 KS (GOST 17648-83) | Aviation, defence, high-reliability products |
Fields of application
Automotive. Intake manifolds, thermostat housings, levers, engine-mount brackets, fan shrouds, pedal assemblies, junction-box housings, air-filter housings. The standard is PA66-GF30 with HSL stabilisation for the under-hood area, and PA6-GF30 for interior brackets.
Aluminium building systems. Thermal breaks (thermal-insulating strips) in the profiles of warm windows and façade systems. The standard is PA66 GF25 for thermal breaks: low thermal conductivity (about 0,30 W/m·K), high dimensional stability under -40…+80 °C temperature swings, resistance to creep under installation load.
Furniture fittings. Five-star bases for office chairs (static load up to 1200 kg per EN 1335-3), load-bearing frames for convertible furniture, fastening elements. The standard is PA6-GF30 (Examid® PA6 GF30, Armamid PA6 GF30-1T), in black with 2% carbon black for UV stability.
Electrical engineering and power tools. Housings for rotary hammers, angle grinders, drills and jigsaws; terminal blocks, connector housings, dielectric bushings. The standard is PA6-GF30 for load-bearing elements, and PA6-GF20 FR / GF25-FR for parts requiring UL 94 V-0. Laser marking of serial numbers uses the LM modification.
Rail transport and heavy machinery. Bearing cages, insulating bushings, housings for contact-network connections. The standard is PA610 KS (weather resistance, low moisture absorption); for cold-resistant applications — Examid® PA6 GF30 62100i (serviceable at -50 °C).
Aerospace and defence. Structural elements made of PA12-GF, PA610-GF, PA612-GF — low moisture absorption is critical for dimensional stability in humid operating conditions. For tender supplies — grades to OST/GOST.
Sporting firearms, agricultural and mining equipment. Housings, stocks, guides — Examid® PA6 GF modifications for two-component moulding with elastomer (soft grips); gearbox brackets — Examid® PA6 GF30, PA66 GF30 with UV stabilisers.
Processing technology for glass-filled polyamides
Drying before moulding is mandatory. Residual moisture in the granulate above 0,2% causes hydrolysis during processing → a loss of 30–60% of mechanical properties, surface defects and bubbles. Regime: 80 °C, 4–6 hours for PA6-GF; 80 °C, 4–8 hours for PA66-GF.
Typical injection-moulding machine zone temperatures:
| Zone | PA6-GF30 | PA66-GF30 |
|---|---|---|
| Feed | 80–90 °C | 85–95 °C |
| Zone 2 | 240–250 °C | 270–280 °C |
| Zone 3 | 255–270 °C | 285–295 °C |
| Zone 4 | 265–280 °C | 290–305 °C |
| Nozzle | 270–290 °C | 295–310 °C |
| Mould temperature | 80–100 °C | 80–120 °C |
Exceeding a melt temperature of 300 °C for PA6 and 320 °C for PA66 leads to thermal degradation of the matrix and brittleness of the part.
Mould. Mould steels should be nitrided or have a hardness of at least HRC 52: glass fibre is abrasive, and soft steels such as P20 wear out within 50 000–200 000 cycles. Hot runners require bushings with carbide or titanium-nitride coatings. Sprues and runners should be of full cross-section, with no sharp corners (to preserve glass-fibre length).
Shrinkage and fibre orientation. Glass fibre orients along the melt flow, so shrinkage along and across the flow differs by a factor of 2–3. This is the main cause of warpage in flat parts. Solutions: balanced mould cooling, gating-system optimisation, symmetrical gates; where necessary — adding a mineral filler (GFGB grades) to reduce shrinkage anisotropy.
Glossary of abbreviations
| Abbreviation | Full form | Meaning |
|---|---|---|
| GF | Glass Fiber | Glass fibre as filler |
| GF30 | 30% glass fibre | Mass content of glass fibre in the compound (%) |
| LGF | Long Glass Fiber | Long glass fibre (>5 mm in the granulate, versus 0,2–0,5 mm in standard GF) |
| HI | High Impact | Impact-resistant modification (with an elastomeric modifier) |
| HSL / HSLR | Heat Stabilized Long-term | Long-term heat stabilisation for 5+ years of service at 150–170 °C |
| LM | Laser Marking | Readiness for high-contrast laser marking |
| FR | Flame Retardant | Flame-retardant modification (UL 94 V-0/V-2) |
| GFGB | Glass Fiber + Glass Bead | Combined filler to reduce warpage |
| DAM | Dry As Molded | Material state immediately after moulding (before conditioning) |
| CON | Conditioned | Material state after conditioning (23 °C / 50% RH) |
| MFR / MFI | Melt Flow Rate / Index | Melt flow rate indicator |
| HDT/A | Heat Deflection Temperature (1,8 MPa) | Heat deflection temperature under a 1,8 MPa load |
| LOI | Limiting Oxygen Index | Limiting oxygen index (a flammability indicator) |
Historical background
Before 1991, Ukraine held a leading position in the production and consumption of glass-filled polyamides (including the automotive sector): the republic was home to the monopolist compounding plant "Skloplastyk" and specialised research institutes. The disruption of logistics chains in the chemical industry and mechanical engineering in the 1990s dealt a fatal blow to the giant, but it also gave impetus to new participants in the polyamide-compound market. This same shift opened the CIS market to international chemical concerns — BASF, DuPont, DSM, Lanxess. Material Wizard continues the Ukrainian engineering tradition of producing glass-filled polyamides of its own formulation under the Examid® brand, combining this technological heritage with modern international quality standards.
Часті запитання
Чому PA GF30 не завжди достатньо для заміни металу?
GF30 підвищує жорсткість і теплостійкість, але полімер все одно має повзучість, анізотропну усадку і нижчий модуль, ніж метал. Для заміни металу потрібна правильна геометрія, ребра, радіуси, напрямок навантаження і контроль орієнтації волокон.
Чому скловолоконний поліамід коробиться?
Скловолокно орієнтується за напрямком потоку розплаву, тому усадка вздовж і поперек потоку різна. Короблення підсилюють нерівномірна товщина стінок, неправильний літник, низька температура форми, дисбаланс охолодження і надмірна жорсткість композиції.
Чим відрізняються PA GF15, GF30, GF40 і GF50?
GF15 дає помірне підсилення і кращу ударну поведінку. GF30 — найпоширеніший баланс жорсткості, міцності та переробки. GF40-GF50 дають високу жорсткість і теплостійкість, але складніші в литті, абразивніші для обладнання і можуть сильніше коробити деталь.
Чому довжина скловолокна важлива?
Довші волокна зазвичай краще передають навантаження і підвищують механічні властивості, але вони можуть руйнуватися під час компаундування і лиття. Надмірний зсув, неправильний шнек або жорсткі режими зменшують ефективну довжину волокна.
Чи можна змішувати скловолоконний поліамід з ненаповненим, щоб знизити жорсткість?
Можна, але потрібно контролювати сумісність, вологість, вміст скла, реологію і стабілізацію. Просте розбавлення може змінити текучість, усадку, поверхню і реальну частку волокна. Для серійного виробництва краще працювати з прогнозованою композицією.
Чому скловолоконні поліаміди швидше зношують обладнання?
Скловолокно абразивне. Воно зношує шнек, циліндр, сопло, гарячі канали і елементи прес-форми. Для високих вмістів скла бажані зносостійкі матеріали обладнання і контроль фактичного стану шнека.
Коли замість скловолокна краще використовувати мінеральний наповнювач або комбінацію GF+MF?
Коли потрібно зменшити короблення, покращити розмірну стабільність або отримати кращу поверхню. Комбінація скловолокна і мінерального наповнювача може давати більш збалансовану усадку, хоча механічні властивості будуть іншими, ніж у чистого GF.