Glass-filled polyamides

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NEW · Hub page

New polyamide selection tools on the PA6 GF30 page

We have built a dedicated technical page for glass-filled PA6 GF30 polyamides: a comparison radar of 13 grades, interactive selection by application, an injection-moulding machine diagram with 7 temperature zones, and a full TDS table for Examid® PA6 GF30 / HI / LM / 62100i.

Go to the PA6 GF30 hub page →
NEW · Hub page

New polyamide selection tools on the PA6 GF50 page

We have built a dedicated technical page for glass-filled PA6 GF50 polyamide (50% glass fibre, modulus ≈16 500 MPa): a comparison radar, interactive selection by application, comparison with PA66 GF50 / PA66 CF30 / PA6 LGF40 and a full TDS table for Examid® PA6 GF50 R10.

Go to the PA6 GF50 hub page →

Glass-filled polyamides (PA GF) are engineering thermoplastics based on the polyamides PA6, PA66, PA610, PA612 and PA12, reinforced with 10–50% glass fibre. Adding glass fibre increases the modulus of elasticity by a factor of 3–4, raises tensile strength by 80–120%, lifts the HDT/A heat resistance from 60 °C to 200–250 °C, and lowers linear moulding shrinkage from 1,4–1,8% to 0,3–0,6%. This makes PA-GF the material of choice for metal replacement in the automotive industry, thermal insulation of aluminium profiles, power-tool housings and load-bearing furniture-fitting components.

Material Wizard manufactures and supplies the Examid® line of glass-filled polyamides (PA6 GF10–GF50, PA66 GF30/GF50, specialised HI / LM / FR / cold-resistant / LGF modifications) and Armamid, and also imports BASF Ultramid, DuPont Zytel, Lanxess Durethan, DSM Akulon, Solvay Technyl, EMS-Grivory, Evonik Vestamid, Akro-Plastic Akromid and RadiciGroup Radilon grades. We select the material to match your drawing, the part's temperature regime and the parameters of your injection-moulding machine.

Key technical properties of PA6-GF30 and PA66-GF30

The figures are given for standard compounds in the dry-as-moulded (DAM) state. Actual lot values are stated in the material's technical data sheet.

PropertyPA6-GF30PA66-GF30Method
Density1,36 g/cm³1,37 g/cm³ISO 1183
Tensile modulus of elasticity9 500 MPa10 000 MPaISO 527
Tensile strength175 MPa185 MPaISO 527
Elongation at break3,5%3,0%ISO 527
Flexural modulus of elasticity9 000 MPa9 500 MPaISO 178
Charpy notched impact strength (23 °C)11 kJ/m²12 kJ/m²ISO 179/1eA
Heat deflection temperature (HDT/A, 1,8 MPa)200 °C250 °CISO 75
Melting temperature220 °C260 °CISO 11357
Processing temperature (melt)260–290 °C280–310 °CTDS
Mould temperature80–100 °C80–120 °CTDS
Water absorption over 24 h at 23 °C1,3%1,1%ISO 62
Water absorption at equilibrium (23 °C / 50% RH)2,6%2,2%ISO 62
Linear shrinkage along the flow0,3–0,5%0,4–0,6%ISO 294-4
Linear shrinkage across the flow0,8–1,2%0,9–1,3%ISO 294-4
Volume resistivity10¹⁴ Ohm·cm10¹⁴ Ohm·cmIEC 60093
Limiting oxygen index LOI (without flame retardants)23%25%ISO 4589

How to choose a glass-filled polyamide — methodology

Step 1. Part operating temperature

Operating temperatureRecommended grade
Up to 90 °C, no contact with hot liquidsPA6-GF30 (Examid® PA6 GF30, Armamid PA6 GF30-1T)
90–130 °C, intermittent heatingPA6-GF30 with a heat stabiliser or PA66-GF30
130–170 °C, continuous loadExamid® PA66 GF30 with HSL stabilisation, analog of Zytel 70G30HSLR
170–230 °C, under-hood areaPPA-GF (polyphthalamide) — a separate category, not a GF polyamide

Step 2. Level of mechanical load

ApplicationRecommended filler level
Decorative and lightly loaded partsGF10–GF15 (low abrasiveness, better surface)
Device housings, medium-load bracketsGF20–GF25
Standard structural parts (most cases)GF30 — the optimum of stiffness, mouldability and price
Metal replacement, high-modulus partsGF40–GF50 (Examid® PA66 GF50, Examid® PA6 GF50 R10)
Load-bearing parts with maximum impact strengthLGF — long glass fibre (Examid® PA6 LGF30)

Step 3. Special requirements

RequirementModification
Impact resistance without loss of stiffnessHI — Examid® PA6 GF30-I
Laser marking of the housingLM — Examid® PA6 GF30 LM
Self-extinguishing V-0 (UL 94)FR — Examid® PA6 GF30 LM
Operation at -40 °C and belowcold-resistant — Examid® PA6 GF30 62100i
Improved surface (visible parts)GFGB with mineral filler — Examid® PA6 GFGB30-6231
Thermal break for aluminium profilesPA66 GF25 for thermal breaks
Contact with fuel, oils, biofuelPA610-GF, PA612-GF

Analogs of imported grades

HSL)
Imported gradeMaterial Wizard analogPurpose
BASF Ultramid B3WG6Examid® PA6 GF30Standard PA6-GF30, housings, brackets
BASF Ultramid A3WG6Examid® PA66 GF30PA66-GF30, heat-stable parts
BASF Ultramid A3WG10Examid® PA66 GF50High-modulus PA66, metal replacement
DuPont Zytel 70G30HSLRExamid® PA66 GF30 (HSL)Long-term service at 150 °C
Long-term service at 150 °C
DuPont Zytel 70G50HSLRExamid® PA66 GF50High-modulus, heat-resistant
Lanxess Durethan BKV30H1.0Examid® PA6 GF30PA6-GF30 with improved flow
DSM Akulon K224-G6Examid® PA6 GF30Standard PA6-GF30
Solvay Technyl A218V30Examid® PA66 GF30Standard PA66-GF30
Akro-Plastic Akromid B3 GF30 1Examid® PA6 GF30PA6-GF30 economy segment
RadiciGroup Radilon S RV300WExamid® PA6 GF30PA6-GF30 for automotive
GOST PA6-211 KSPA6 210 KS premium grade (OST 6-11-498-79)Tender supplies
GOST PA66 KSPA66 KS premium grade (OST 6-11-498-79)Tender supplies
GOST PA610 KSPA610 KS (GOST 17648-83)Aviation, defence, high-reliability products

Fields of application

Automotive. Intake manifolds, thermostat housings, levers, engine-mount brackets, fan shrouds, pedal assemblies, junction-box housings, air-filter housings. The standard is PA66-GF30 with HSL stabilisation for the under-hood area, and PA6-GF30 for interior brackets.

Aluminium building systems. Thermal breaks (thermal-insulating strips) in the profiles of warm windows and façade systems. The standard is PA66 GF25 for thermal breaks: low thermal conductivity (about 0,30 W/m·K), high dimensional stability under -40…+80 °C temperature swings, resistance to creep under installation load.

Furniture fittings. Five-star bases for office chairs (static load up to 1200 kg per EN 1335-3), load-bearing frames for convertible furniture, fastening elements. The standard is PA6-GF30 (Examid® PA6 GF30, Armamid PA6 GF30-1T), in black with 2% carbon black for UV stability.

Electrical engineering and power tools. Housings for rotary hammers, angle grinders, drills and jigsaws; terminal blocks, connector housings, dielectric bushings. The standard is PA6-GF30 for load-bearing elements, and PA6-GF20 FR / GF25-FR for parts requiring UL 94 V-0. Laser marking of serial numbers uses the LM modification.

Rail transport and heavy machinery. Bearing cages, insulating bushings, housings for contact-network connections. The standard is PA610 KS (weather resistance, low moisture absorption); for cold-resistant applications — Examid® PA6 GF30 62100i (serviceable at -50 °C).

Aerospace and defence. Structural elements made of PA12-GF, PA610-GF, PA612-GF — low moisture absorption is critical for dimensional stability in humid operating conditions. For tender supplies — grades to OST/GOST.

Sporting firearms, agricultural and mining equipment. Housings, stocks, guides — Examid® PA6 GF modifications for two-component moulding with elastomer (soft grips); gearbox brackets — Examid® PA6 GF30, PA66 GF30 with UV stabilisers.

Processing technology for glass-filled polyamides

Drying before moulding is mandatory. Residual moisture in the granulate above 0,2% causes hydrolysis during processing → a loss of 30–60% of mechanical properties, surface defects and bubbles. Regime: 80 °C, 4–6 hours for PA6-GF; 80 °C, 4–8 hours for PA66-GF.

Typical injection-moulding machine zone temperatures:

ZonePA6-GF30PA66-GF30
Feed80–90 °C85–95 °C
Zone 2240–250 °C270–280 °C
Zone 3255–270 °C285–295 °C
Zone 4265–280 °C290–305 °C
Nozzle270–290 °C295–310 °C
Mould temperature80–100 °C80–120 °C

Exceeding a melt temperature of 300 °C for PA6 and 320 °C for PA66 leads to thermal degradation of the matrix and brittleness of the part.

Mould. Mould steels should be nitrided or have a hardness of at least HRC 52: glass fibre is abrasive, and soft steels such as P20 wear out within 50 000–200 000 cycles. Hot runners require bushings with carbide or titanium-nitride coatings. Sprues and runners should be of full cross-section, with no sharp corners (to preserve glass-fibre length).

Shrinkage and fibre orientation. Glass fibre orients along the melt flow, so shrinkage along and across the flow differs by a factor of 2–3. This is the main cause of warpage in flat parts. Solutions: balanced mould cooling, gating-system optimisation, symmetrical gates; where necessary — adding a mineral filler (GFGB grades) to reduce shrinkage anisotropy.

Glossary of abbreviations

AbbreviationFull formMeaning
GFGlass FiberGlass fibre as filler
GF3030% glass fibreMass content of glass fibre in the compound (%)
LGFLong Glass FiberLong glass fibre (>5 mm in the granulate, versus 0,2–0,5 mm in standard GF)
HIHigh ImpactImpact-resistant modification (with an elastomeric modifier)
HSL / HSLRHeat Stabilized Long-termLong-term heat stabilisation for 5+ years of service at 150–170 °C
LMLaser MarkingReadiness for high-contrast laser marking
FRFlame RetardantFlame-retardant modification (UL 94 V-0/V-2)
GFGBGlass Fiber + Glass BeadCombined filler to reduce warpage
DAMDry As MoldedMaterial state immediately after moulding (before conditioning)
CONConditionedMaterial state after conditioning (23 °C / 50% RH)
MFR / MFIMelt Flow Rate / IndexMelt flow rate indicator
HDT/AHeat Deflection Temperature (1,8 MPa)Heat deflection temperature under a 1,8 MPa load
LOILimiting Oxygen IndexLimiting oxygen index (a flammability indicator)

Historical background

Before 1991, Ukraine held a leading position in the production and consumption of glass-filled polyamides (including the automotive sector): the republic was home to the monopolist compounding plant "Skloplastyk" and specialised research institutes. The disruption of logistics chains in the chemical industry and mechanical engineering in the 1990s dealt a fatal blow to the giant, but it also gave impetus to new participants in the polyamide-compound market. This same shift opened the CIS market to international chemical concerns — BASF, DuPont, DSM, Lanxess. Material Wizard continues the Ukrainian engineering tradition of producing glass-filled polyamides of its own formulation under the Examid® brand, combining this technological heritage with modern international quality standards.

Часті запитання

Чому PA GF30 не завжди достатньо для заміни металу?

GF30 підвищує жорсткість і теплостійкість, але полімер все одно має повзучість, анізотропну усадку і нижчий модуль, ніж метал. Для заміни металу потрібна правильна геометрія, ребра, радіуси, напрямок навантаження і контроль орієнтації волокон.

Чому скловолоконний поліамід коробиться?

Скловолокно орієнтується за напрямком потоку розплаву, тому усадка вздовж і поперек потоку різна. Короблення підсилюють нерівномірна товщина стінок, неправильний літник, низька температура форми, дисбаланс охолодження і надмірна жорсткість композиції.

Чим відрізняються PA GF15, GF30, GF40 і GF50?

GF15 дає помірне підсилення і кращу ударну поведінку. GF30 — найпоширеніший баланс жорсткості, міцності та переробки. GF40-GF50 дають високу жорсткість і теплостійкість, але складніші в литті, абразивніші для обладнання і можуть сильніше коробити деталь.

Чому довжина скловолокна важлива?

Довші волокна зазвичай краще передають навантаження і підвищують механічні властивості, але вони можуть руйнуватися під час компаундування і лиття. Надмірний зсув, неправильний шнек або жорсткі режими зменшують ефективну довжину волокна.

Чи можна змішувати скловолоконний поліамід з ненаповненим, щоб знизити жорсткість?

Можна, але потрібно контролювати сумісність, вологість, вміст скла, реологію і стабілізацію. Просте розбавлення може змінити текучість, усадку, поверхню і реальну частку волокна. Для серійного виробництва краще працювати з прогнозованою композицією.

Чому скловолоконні поліаміди швидше зношують обладнання?

Скловолокно абразивне. Воно зношує шнек, циліндр, сопло, гарячі канали і елементи прес-форми. Для високих вмістів скла бажані зносостійкі матеріали обладнання і контроль фактичного стану шнека.

Коли замість скловолокна краще використовувати мінеральний наповнювач або комбінацію GF+MF?

Коли потрібно зменшити короблення, покращити розмірну стабільність або отримати кращу поверхню. Комбінація скловолокна і мінерального наповнювача може давати більш збалансовану усадку, хоча механічні властивості будуть іншими, ніж у чистого GF.