{"id":2385,"date":"2021-03-25T14:33:22","date_gmt":"2021-03-25T11:33:22","guid":{"rendered":"https:\/\/materialwizard.com.ua\/?p=2385"},"modified":"2026-06-07T08:47:40","modified_gmt":"2026-06-07T05:47:40","slug":"kraton-d1184-asm","status":"publish","type":"post","link":"https:\/\/materialwizard.com.ua\/en\/kraton-d1184-asm\/","title":{"rendered":"Block copolymer KRATON D1184 ASM"},"content":{"rendered":"<p><\/p>\n<h3>Description<\/h3>\n<p>KRATON\u00ae D1184 ASM is an asymmetric (branched) styrene-butadiene block copolymer (SBS) produced by Kraton Corporation. Grade designation: D \u2014 diene (butadiene)-based SBS series, 1184 \u2014 internal formulation index, ASM \u2014 Asymmetric (a branched molecular architecture with radial, star-shaped chains, as opposed to the linear D series).<\/p>\n<p>The styrene content of 30 wt % is a medium concentration that provides a balance of strength and elasticity. The branched architecture gives D1184 ASM three critically important properties that set it apart from linear SBS: <strong>1)<\/strong> low melt viscosity at standard processing temperatures \u2014 easier hot-melt processing and adhesive application; <strong>2)<\/strong> high cohesive strength \u2014 the adhesive does not flow under load; <strong>3)<\/strong> retention of elasticity over a wide temperature range.<\/p>\n<p>Supplied as a <strong>powder<\/strong> dusted with amorphous silica (anti-block agent) to prevent caking during storage and transport. This is a distinctive feature of D1184 ASM compared with pelletized SBS grades, which are more convenient for pellet feeding of extruders but less effective for direct hot-melt compounding.<\/p>\n<p>Typical parameters: polystyrene content 30 wt %, MFR ~5\u201310 g\/10 min (200 \u00b0C \/ 5 kg), Mooney viscosity ML(1+4) 100 \u00b0C \u2248 50, Shore A hardness ~65\u201375, tensile strength 25\u201330 MPa, elongation at break 700\u2013900 %, compression set 30\u201340 % at 70 \u00b0C \/ 22 h. Density 0.94 g\/cm\u00b3.<\/p>\n<h3>Key advantages<\/h3>\n<ul>\n<li><strong>Low melt viscosity<\/strong> \u2014 easier hot-melt processing, lower compounding energy consumption<\/li>\n<li><strong>High cohesive strength<\/strong> combined with high adhesion \u2014 an ideal balance for PSA (pressure-sensitive adhesives)<\/li>\n<li><strong>Branched architecture<\/strong> \u2014 better hot-melt stability compared with linear SBS<\/li>\n<li>Good solubility in hydrocarbon solvents (toluene, cyclohexane) \u2014 for solvent-based adhesives<\/li>\n<li>Compatibility with hydrocarbon resins and paraffins for tackifier formulation<\/li>\n<li>Elasticity down to \u221240 \u00b0C \u2014 suitable for cold climates<\/li>\n<li>Standard styrene content of 30 % \u2014 a balance of strength and elasticity (for higher adhesion \u2014 D-series grades with 15-20% styrene, for higher strength \u2014 40 %)<\/li>\n<li>Powder form with anti-block \u2014 easy dosing into compounding equipment<\/li>\n<\/ul>\n<h3>Applications<\/h3>\n<ul>\n<li><strong>Hot-melt adhesives (HMA):<\/strong> industrial hot-melt adhesives for packaging, carton converting, furniture edging and lamination \u2014 the main market for D1184 ASM<\/li>\n<li><strong>Pressure-sensitive adhesives (PSA):<\/strong> hot-melt adhesives for self-adhesive labels, tapes, medical plasters and hygiene products (diapers, feminine hygiene)<\/li>\n<li><strong>Adhesives for hygiene products:<\/strong> construction and elastic adhesives in the manufacture of diapers and sanitary pads \u2014 bonding nonwovens, elastic strips, tampons<\/li>\n<li><strong>Construction adhesives and sealants:<\/strong> assembly adhesives based on hydrocarbon resins, silicone and SBS sealants<\/li>\n<li><strong>Bitumen modifier (PMB):<\/strong> addition of 3\u20135 % to bitumen to improve the elastic-plastic properties of asphalt concrete and extend the service temperature range of road pavements (polymer-modified bitumen)<\/li>\n<li><strong>Roofing mastics and membranes:<\/strong> bituminous roofing materials with improved elasticity and crack resistance<\/li>\n<li><strong>Shoe soles:<\/strong> compounding with other SBS \/ SBR \/ extender oils for the production of soles for sports and casual footwear<\/li>\n<li><strong>Plastics modifier:<\/strong> impact modifier for PS and PP at 5\u201315 % loading \u2014 increases impact strength, especially at low temperatures<\/li>\n<\/ul>\n<h3>Limitations<\/h3>\n<ul>\n<li>SBS is an unsaturated elastomer; <strong>not for long-term outdoor service under UV exposure<\/strong> without UV stabilization (for outdoor use \u2014 hydrogenated SEBS grades, e.g. the Kraton G series)<\/li>\n<li>Sensitivity to ozone \u2014 cracking of surface layers at ozone concentrations >0.1 ppm<\/li>\n<li>Not for contact with aromatic solvents (dissolves in toluene and xylene)<\/li>\n<li>Not for continuous high-temperature service above 80 \u00b0C (Tg of the polystyrene blocks is ~95 \u00b0C \u2014 cohesive strength is lost above this)<\/li>\n<\/ul>\n<p><em>Global market counterparts: ENI Versalis Europrene\u00ae Sol T 161 (linear SBS 30 %), Total Cray Valley Calprene\u00ae C 540 (radial SBS), Asahi Kasei Tufprene\u00ae A (linear SBS), LCY Globalprene\u00ae 3540 (radial SBS). KRATON\u00ae is the original brand of Kraton Corporation (USA\/Netherlands).<\/em><\/p>\n<p><em>The stated values are measured using in-house methods close to the corresponding ISO, ASTM and GOST standards. This information is for reference only and does not constitute an official batch data sheet. Please request the TDS and MSDS for the specific batch before industrial use.<\/em><\/p>\n<p><\/p>","protected":false},"excerpt":{"rendered":"<p>Description KRATON\u00ae D1184 ASM is an asymmetric (branched) styrene-butadiene block copolymer (SBS) produced by Kraton Corporation. Grade designation: D \u2014 diene (butadiene)-based SBS series, 1184 \u2014 internal formulation index, ASM \u2014 Asymmetric (a branched molecular architecture with radial, star-shaped chains, as opposed to the linear D series). The styrene content of 30 wt % is [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":2391,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[10,37],"tags":[],"class_list":["post-2385","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-modifiers","category-bitumen-modifiers"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.7 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Block copolymer KRATON D1184 ASM &#8212; MaterialWizard<\/title>\n<meta name=\"description\" content=\"KRATON D1184 ASM \u2014 clear branched SBS block copolymer with 30 % bound styrene. High strength, low melt viscosity, easy processing. 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